Update 9th May 2013: Not in the top 10 for size, but a little known rock formation in Australia:

Kissing Rocks

From AmusingPlanet.com and The Natural Arch and Bridge Society

A natural arch is a geological formation where rocky cliffs subject to erosion from the sea, rivers or weathering forms a rock arch. Some natural arch has a stream of water flowing underneath, in which case the arch is called a natural bridge. The distinction between a bridge and arch is somewhat arbitrary. The Natural Arch and Bridge Society identifies a bridge as a subtype of arch that is primarily water-formed. By contrast, the Dictionary of Geological Terms defines a natural bridge as a “natural arch that spans a valley of erosion.” The correct method to measure an arch is also debated because of which the reported measurements often varies from source to source. Under these circumstances to prepare an irrefutable list of the world’s largest or longest or highest natural arch is impossible. Amidst this confusion new discoveries and potential candidates always keep popping up around the globe.

Natural arches are abundant in the deserts of Utah and Arizona in the United States. The Arches National Park in eastern Utah contains the largest concentration of significant natural arches in the world. As many as 2000 natural sandstone arches, including the world-famous Delicate Arch, in addition to a variety of unique geological resources and formations are found in this region.

See AmusingPlanet.com for more photos and details of the 10 biggest natural arches from around the world according to the Natural Arch and Bridge Society